gaussian里的PCM低估反应能垒,校正常数是多少?

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说gaussian里的溶剂模型如CPCM,IEFPCM溶剂模型会低估反应能垒(二面角转动能垒),应该有个经验的校正常数吧?比如gaussian算红外振动光谱,不同方法和基组都会有个经验的校正常数,大致都是在0.8左右,校正之后可以和实验对比。有没有讨论这方面的文献?